The voltage drop over the power diodes in your diode splitter is most likely to be 1,1 .. 1,2 Volts when a large charging current is feeding your maintenance battery.
The voltage drop over the power diode feeding your starter battery is 0,6 .. 0,7 Volts since (almost) no charge current is flowing to your starter battery.
Since the sense wire is connected to your maintenance battery, the voltage of the starter battery will be 0,5 .. 0,6 Volts higher than the load voltage on the maintenance battery.
Depending on the voltage regulator in your alternator, the sense voltage setting is most likely 14,2.
A load voltage of a starter battery of 14,8 V can be expected for short duration time.
When the maintenanc battery get loaded, the load current decreases and the voltage difference will also decrease until both batteries will have same loading voltage.
It's all quite easy to measure with a voltmeter by measuring the voltage drop over both power diodes of your diode bridge
When the voltage drop appears to be higher than 1,2 Volts, the diode bridge is most likely damaged.
When you end up in situations that your maintenance battery is often depleted, an argofet diode bridge is a good solution since voltage drop over the diodes is limited even by large current flows.