The marked connector is neither D nor W. It is the voltage sensing input for the alternator regulator. If disconnected, your alternator charges with full power, until the voltage reaches 14,4V (measured on B Connector of alternator). If you connect this terminal to your house bank, which has lower voltage than 14,4V , the regulator will force the alternator to generate more current/power to bring your battery up to 14,4V and reduce power when the house bank reaches 14,4v. This circuitry serves as compensation for the voltage losses on cables, diodesplitters in the charging path. In your case (blown diode splitter) the sensing input remained on 13,something Volts, forcing the alternator to produce maximum power, which only could go to the starter battery (the path in diodesplitter to housebank was blown) , causing the Over voltage alarm and probably cooked your starter battery.