Irrespective of which engine the OP has and the size of the alternator, most Volvo Pentas use a battery sensed alternator. There’s a thin (usually yellow) wire which runs from the alternator to the positive terminal of the batteries. If you don’t disconnect that wire from the batteries and connect it to the B+ terminal on the back of the alternator (turning it into a machine sensed alternator) then the Sterling AtoB will do little or nothing.
Cut the yellow wire reasonably close to the alternator, fit a ring crimp terminal and connect that to the B+ terminal on the alternator. Use the yellow wire, still connected to the +ve terminal of the batteries, to connect to the battery voltage sensor of the AtoB.
If that’s already been done, no idea what’s the matter!