You'll probably find it difficult to upgrade the alternator's internal regulator. You could fit an alternator booster (Sterling, Adverc, etc) and this will increase the charge voltage and also make it battery-sensing (so will overcome voltage drops in cables, diodes, etc). Or you could fit a Sterling Alternator-to-Battery charger, which supplies a boosted output to the service batteries and an unboosted separate output to the starter battery. One advantage of this unit is that there's no need to make any modifications to the alternator (which are needed with simple boosters).